Larger hard spheres in spherical confinement are entropically driven to and trapped at the vertices of icosahedral clusters formed by smaller spheres.
Crystallization of Nanocrystals in Spher- ical Confinement Probed by in Situ X-ray Scattering,
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Entropic Trapping of Hard Spheres in Spherical Confinement
Larger hard spheres in spherical confinement are entropically driven to and trapped at the vertices of icosahedral clusters formed by smaller spheres.