A new on-surface synthesis motif produces gulf-edged chiral graphene nanoribbons identified as closed-shell semiconductors with a 1.8 eV bandgap, distinctive Raman modes, and unexpected ambient instability.
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Electron capture at zigzag edges stabilizes armchair GNRs, eliminates spin polarization in the ground state, and induces Fermi level pinning with valence and conduction band slopes of approximately 0.1 and 0.9.
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Electronic and Vibrational Properties of On-Surface Synthesized Gulf-Edged Chiral Graphene Nanoribbons
A new on-surface synthesis motif produces gulf-edged chiral graphene nanoribbons identified as closed-shell semiconductors with a 1.8 eV bandgap, distinctive Raman modes, and unexpected ambient instability.
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Electron enrichment of zigzag edges of armchair-oriented graphene nano-ribbons increases their stability and induces pinning of Fermi level
Electron capture at zigzag edges stabilizes armchair GNRs, eliminates spin polarization in the ground state, and induces Fermi level pinning with valence and conduction band slopes of approximately 0.1 and 0.9.