RIXS measurements and cluster calculations determine opposite trigonal distortions in VBr3 (-0.096 eV) and VI3 (0.07 eV), yielding distinct high-spin V3+ ground states.
X-ray absorption spectroscopy of vanadium dioxide thin films across the phase-transition boundary.Physical Review B—Condensed Matter and Materials Physics, 75(19):195102, 2007
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Trigonal Distortion Driven Ground States in VX3 (X = Br and I)
RIXS measurements and cluster calculations determine opposite trigonal distortions in VBr3 (-0.096 eV) and VI3 (0.07 eV), yielding distinct high-spin V3+ ground states.