Kink scattering of phonons, effective even in the long-wavelength limit, causes thermal conductivity to drop with chain length for random orientations, explaining alignment sensitivity in polymers.
\ Leitner ,\ title title Vibrational energy transfer and heat conduction in a one-dimensional glass , \ 10.1103/PhysRevB.64.094201 journal journal Phys
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How alignment controls heat transport in polymer chains with kinks?
Kink scattering of phonons, effective even in the long-wavelength limit, causes thermal conductivity to drop with chain length for random orientations, explaining alignment sensitivity in polymers.