Machine-learned many-body potentials from Poisson-Boltzmann calculations on clusters up to 48 colloids show that higher-order interactions reduce cohesion and eliminate broad gas-liquid phase separation, consistent with primitive model pair and triplet potentials.
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Asymptotic analysis of the PNP model for asymmetric-valence electrolytes yields a valence-dependent transition current at which the Debye layer vanishes, plus explicit composite solutions for 2z:z, z:2z and z:z cases and a collapsed phase diagram.
Salt stabilises a 5 nm Newton black film in vertical soap films, extending their lifetime at all humidities, while drainage and evaporation dynamics remain unchanged down to 100 nm.
Analytic solutions to the linear modified Poisson-Boltzmann equation predict a transition to damped oscillatory screening in electrolytes above a critical concentration.
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Many-body attractions do not stabilize gas-liquid phase separation in aqueous dispersions of charged colloids within the Poisson-Boltzmann framework
Machine-learned many-body potentials from Poisson-Boltzmann calculations on clusters up to 48 colloids show that higher-order interactions reduce cohesion and eliminate broad gas-liquid phase separation, consistent with primitive model pair and triplet potentials.
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Modelling Intermediate-Current Transitions in Asymmetric-Valence Binary Electrolytes
Asymptotic analysis of the PNP model for asymmetric-valence electrolytes yields a valence-dependent transition current at which the Debye layer vanishes, plus explicit composite solutions for 2z:z, z:2z and z:z cases and a collapsed phase diagram.
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Stabilising Evaporating Soap Films with Salt
Salt stabilises a 5 nm Newton black film in vertical soap films, extending their lifetime at all humidities, while drainage and evaporation dynamics remain unchanged down to 100 nm.
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Comments on the linear modified Poisson-Boltzmann equation in electrolyte solution theory
Analytic solutions to the linear modified Poisson-Boltzmann equation predict a transition to damped oscillatory screening in electrolytes above a critical concentration.