Surface polarons on rutile TiO2(110) suppress water dissociation at polaronic sites by about 240 meV, slightly enhance it at some non-polaronic sites, and strengthen hydrogen bonds between adsorbed water and hydroxide.
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Small polarons and the Janus nature of $\text{TiO}_\text{2}(110)$
Surface polarons on rutile TiO2(110) suppress water dissociation at polaronic sites by about 240 meV, slightly enhance it at some non-polaronic sites, and strengthen hydrogen bonds between adsorbed water and hydroxide.