Operando electron microscopy reveals a four-stage field-driven pathway in PbZrO3 from antiferroelectric through a monoclinic ferroelectric intermediate to rhombohedral and tetragonal ferroelectric states, with a dead layer near the substrate.
Theory of antiferroelectric crystals.Phys
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Direct determination of antiferroelectric-to-ferroelectric phase transition pathways in PbZrO$_3$ with Operando Electron Microscopy
Operando electron microscopy reveals a four-stage field-driven pathway in PbZrO3 from antiferroelectric through a monoclinic ferroelectric intermediate to rhombohedral and tetragonal ferroelectric states, with a dead layer near the substrate.