Simulations show micelle chain escape follows the collapsed-globule Halperin-Alexander path with an N^(2/3) barrier when the core can collapse, but an extended bead-by-bead path with a linear barrier when it cannot.
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Mechanisms of Chain Exchange in Diblock Copolymer Micelles
Simulations show micelle chain escape follows the collapsed-globule Halperin-Alexander path with an N^(2/3) barrier when the core can collapse, but an extended bead-by-bead path with a linear barrier when it cannot.