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arxiv: 0705.4675 · v1 · submitted 2007-05-31 · ❄️ cond-mat.mtrl-sci

Thermal expansion and pressure effect in MnWO4

classification ❄️ cond-mat.mtrl-sci
keywords phasepressurecommensurateeffectexpansionferroelectricmagneticmnwo4
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MnWO4 has attracted attention because of its ferroelectric property induced by frustrated helical spin order. Strong spin-lattice interaction is necessary to explain ferroelectricity associated with this type of magnetic order.We have conducted thermal expansion measurements along the a, b, c axes revealing the existence of strong anisotropic lattice anomalies at T1=7.8 K, the temperature of the magnetic lock-in transition into a commensurate low-temperature (reentrant paraelectric) phase. The effect of hydrostatic pressure up to 1.8 GPa on the FE phase is investigated by measuring the dielectric constant and the FE polarization. The low- temperature commensurate and paraelectric phase is stabilized and the stability range of the ferroelectric phase is diminished under pressure.

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