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arxiv: 0803.0801 · v1 · submitted 2008-03-06 · ⚛️ physics.atom-ph · physics.chem-ph

Singular Hylleraas three-electron integrals

classification ⚛️ physics.atom-ph physics.chem-ph
keywords integralselectronformhylleraassingularbasiscalculationscoordinates
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Calculations of the leading quantum electrodynamics effects in few electron systems involve singular matrix elements of the inter-electronic distances of the form $1/r_i^3$ and $1/r_{ij}^3$. Integrals that result when the nonrelativistic wave function is represented with a Hylleraas basis representation are studied. Recursion relations for various powers of the electron coordinates and the master integrals are derived in a form suited for high precision numerical evaluations.

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