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arxiv: 0804.0567 · v2 · submitted 2008-04-03 · 🪐 quant-ph

Ionisation of hydrogen molecule in intense ultrashort laser pulses: parallel versus perpendicular orientation

classification 🪐 quant-ph
keywords laserhydrogenionisationparallelperpendicularphotonpulseapproximation
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A theoretical comparison of the electronic excitation and ionisation behaviour of molecular hydrogen oriented either parallel or perpendicular to a linear polarised laser pulse is performed. The investigation is based on a non-perturbative treatment that solves the full time-dependent Schr\"odinger equation of both correlated electrons within the fixed-nuclei approximation and the dipole. Results are shown for two different laser pulse lengths and intensities as well as for a large variety of photon frequencies starting in the 1- and reaching into the 6-photon regime. In order to investigate the influence of the intrinsic diatomic two-center problem even further, two values of the internuclear separation and a newly developed atomic model are considered.

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