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arxiv: 0806.2049 · v1 · submitted 2008-06-12 · 🪐 quant-ph

Vibrational spectroscopy of H2+: hyperfine structure of two-photon transitions

classification 🪐 quant-ph
keywords two-photonhyperfinespectroscopystructurecomputationdiscusseffectselements
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We present the computation of two-photon transition spectra between ro-vibrational states of the H2+ molecular ion, including the effects of hyperfine structure and excitation polarization. The reduced two-photon matrix elements are obtained by means of a variational method. We discuss the implications of our results for high-resolution spectroscopy of H2+.

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