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arxiv: 0808.1190 · v1 · submitted 2008-08-08 · ⚛️ physics.chem-ph

Restricted Open-Shell Kohn-Sham Theory IV: Expressions for N Unpaired Electrons

classification ⚛️ physics.chem-ph
keywords electronsunpairedenergyexpressionkohn-shammultipletsopen-shellrestricted
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We present an energy expression for restricted open-shell Kohn-Sham theory for N unpaired electrons and single-electron operators for all multiplets formed from up to five unpaired electrons. It is shown that it is possible to derive an explicit energy expression for all low-spin multiplets of systems that exhibit neither radial nor cylindrical symmetry.

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