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arxiv: 0808.3271 · v1 · submitted 2008-08-24 · ❄️ cond-mat.stat-mech

Reply to Comment on "Failure of the work-Hamiltonian connection for free-energy calculations" by Horowitz and Jarzynski

classification ❄️ cond-mat.stat-mech
keywords horowitzjarzynskichangecommentenergyarxivcalculationschanges
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We show that the Comment [arXiv:0808.1224] by Horowitz and Jarzynski obtains as a main result a general free energy change for a harmonic system that in the macroscopic limit does not recover the textbook expression for the energy change of a Hookean spring. The reason is that Horowitz and Jarzynski improperly identify work with parametric changes of the Hamiltonian instead of with the standard quantity, force times displacement.

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