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arxiv: 0812.0798 · v1 · submitted 2008-12-03 · ❄️ cond-mat.mtrl-sci

A new class of organic molecular magnets

classification ❄️ cond-mat.mtrl-sci
keywords bridgemolecularmoleculesorganicclasslengthmagneticmagnets
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Using detailed first principles calculations, we have found a new class of stable organic molecular magnets based on zwitterionic molecules possessing donor, $\pi$ bridge, and acceptor groups. These molecules are organic molecules containing only C, H and N. The quantum mechanical nature of the magnetic properties originates from the conjugated $\pi$ bridge (involving only p electrons) where the exchange interactions between electron spin are relatively strong and local and are independent of the length of the $\pi$ bridge, enabling the easy construction of a molecular magnetic device with specified length.

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