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arxiv: 0907.3116 · v1 · submitted 2009-07-17 · 🪐 quant-ph

Rotating Morse wave packet dynamics of diatomic molecule

classification 🪐 quant-ph
keywords moleculediatomicdynamicsmorsepacketrotatingspacewave
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We investigate the dynamics of a rotating Morse wave packet, appropriate for a ro-vibrating diatomic molecule. The coupling between vibrational and rotational degrees of freedom is explicated in real position space as well as in phase space Wigner distribution of a SU(2) coherent state at various dynamically evolved times. We choose the well studied $I_{2}$ molecule with the parameter values in good agrement with experiments. A quantitative measure of the angles of rotations for different angular momenta is also given.

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