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arxiv: 0910.4365 · v1 · pith:RAG7ZCO3new · submitted 2009-10-22 · 🪐 quant-ph

Superscars in the LiNC=LiCN isomerization reaction

classification 🪐 quant-ph
keywords isomerizationlicnlincpotentialreactionappearingarisesattainable
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We demonstrate the existence of superscarring in the LiNC=LiCN isomerization reaction described by a realistic potential interaction in the range of readily attainable experimental energies. This phenomenon arises as the effect of two periodic orbits appearing "out of the blue"in a saddle--node bifurcation taking place in the dynamics of the system. Potential practical consequences of this superlocalization in the corresponding wave functions are also considered.

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