Spectroscopy of nickel monosulfide in 450 - 560 nm by laser-induced fluorescence and dispersed fluorescence techniques

Laser-induced fluorescence excitation spectrum of NiS in the wavelength range of 450 - 560 nm has been recorded and analyzed. Thirty-five vibronic transition bands have been observed, 29 of which are reported for the first time. Rotational analyses indicated that all the observed bands can be attributable to the [Omega = 0] - X^3 Sigma^- transitions of ^58 NiS (and ^60 NiS). Twenty-five bands have been suggested to be grouped into four vibrational progressions. Furthermore, through dispersed fluorescence measurements we directly obtained the energies for the ground-state vibrational levels up to v" = 6 as well as the vibrational frequency and the anharmonicity constant for the ground state of ^58 NiS.