Structural, electrical, magnetic and thermal studies of Cr-doped La0.7Ca0.3Mn1-xCrxO3 for x = 0.0 to 1.0 manganites

We report detailed structural, electrical, magnetic and specific heat studies on La0.7Ca0.3Mn1-xCrxO3 manganites. Rietveld analysis of fitted and observed XRD patterns exhibited the single-phase nature of all the studied materials, which crystallize in Pbnm space group. Successive substitution of Cr at Mn site in La0.7Ca0.3Mn1-xCrxO3 manganites increases the electrical resistivity and decrease the characteristic insulator-metal transition temperature (TIM) of the parent compound along with a hump like feature for higher Cr-content samples. The hump structure basically signifies the onset of anti-ferromagnetic (AFM) interactions as inferred by both the magnetic and infra-red (IR) spectroscopy studies. The systematic suppression of FM state results in a spin glass (SG) like behavior. IR studies revealed that the vibration mode at 413 cm-1 being associated with internal bending of MnO6 octehedra, becomes softer, indicating an increase in distortion and hence the possible spin glass behavior. The critical exponents alpha, beta and gama are calculated from the heat capacity (CP) data near the TIM/TFM. The same exhibited variations of their values with doping. In particular the value of beta increases from 0.37 to 0.43, clearly indicating the coexistence of both long and short range magnetic orders i.e. tendency towards SG state for Cr doped samples. On the basis of present results, it is suggested that Cr dilutes double-exchange (DE) based FM and rather promotes the AFM based super exchange interactions (SE) via Cr3+/Mn4+ ions. Substitution of Cr systematically destroys both the metallic state and long range ferromagnetic (FM) order.