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arxiv: 1010.3244 · v1 · pith:QNVBO5NPnew · submitted 2010-10-15 · ❄️ cond-mat.mes-hall

The effect of confinement on the interaction between two like-charged rods

classification ❄️ cond-mat.mes-hall
keywords rodsattractionchargedconfinementelectrolyteimmersedbilayerscarlo
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Monte Carlo simulations were employed to study two charged rods confined between two unlike charged plates, all immersed in a model electrolyte. Recently, it was shown that two rods immersed in a multivalent counterion solution may show attraction (PRL 78, 2477 (1997)). Here we show for a monovalent electrolyte that rod-rod attraction and repulsion can switch sign depending on confinement and ionic size. We also propose a simple self-assembling mechanism which may be helpful to understand the DNA-lipid bilayers complexation.

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