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arxiv: 1101.2400 · v1 · pith:XQPXVKEZnew · submitted 2011-01-12 · ❄️ cond-mat.soft

Clustering, conductor-insulator transition and phase separation of an ultrasoft model of electrolytes

classification ❄️ cond-mat.soft
keywords modelphaseseparationclusteringconductor-insulatortransitionultrasoftbelow
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We investigate the clustering and phase separation of a model of ultrasoft, oppositely charged macroions by a combination of Monte Carlo and Molecular Dynamics simulations. Static and dynamic diagnostics, including the dielectric permittivity and the electric conductivity of the model, show that ion pairing induces a sharp conductor-insulator transition at low temperatures and densities, which impacts the separation into dilute and concentrated phases below a critical temperature. Preliminary evidence is presented for a possible tricritical nature of the phase diagram of the model.

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