Thermal Expansion Coefficients of Bi₂Se₃ and Sb₂Te₃ Crystals from 10 K to 270 K

Lattice constant of Bi$_2$Se$_3$ and Sb$_2$Te$_3$ crystals is determined by X-ray powder diffraction measurement in a wide temperature range. Linear thermal expansion coefficients ($\alpha$) of the crystals are extracted, and considerable anisotropy between $\alpha_\parallel$ and $\alpha_\perp$ is observed. The low temperature values of $\alpha$ can be fit well by the Debye model, while an anomalous behavior at above 150 K is evidenced and explained. Gr\"uneisen parameters of the materials are also estimated at room temperature.