Computational investigation of static multipole polarizabilities and sum rules for ground-state hydrogen-like ions
classification
⚛️ physics.atom-ph
physics.chem-ph
keywords
polarizabilitiesmultipolerulesaccuracyalphaanalyticb-splineboundary
read the original abstract
High precision multipole polarizabilities, $\alpha_{\ell}$ for $\ell \le 4$ of the $1s$ ground state of the hydrogen isoelectronic series are obtained from the Dirac equation using the B-spline method with Notre Dame boundary conditions. Compact analytic expressions for the polarizabilities as a function of $Z$ with a relative accuracy of 10$^{-6}$ up to $Z = 100$ are determined by fitting to the calculated polarizabilities. The oscillator strengths satisfy the sum rules $\sum_i f^{(\ell)}_{0i} = 0$ for all multipoles from $\ell = 1$ to $\ell = 4$. The dispersion coefficients for the long-range H-H and H-He$^+$ interactions are given.
This paper has not been read by Pith yet.
discussion (0)
Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.