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arxiv: 1205.6883 · v1 · pith:PSRYYTNZnew · submitted 2012-05-31 · ⚛️ physics.atom-ph · physics.chem-ph

Computational investigation of static multipole polarizabilities and sum rules for ground-state hydrogen-like ions

classification ⚛️ physics.atom-ph physics.chem-ph
keywords polarizabilitiesmultipolerulesaccuracyalphaanalyticb-splineboundary
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High precision multipole polarizabilities, $\alpha_{\ell}$ for $\ell \le 4$ of the $1s$ ground state of the hydrogen isoelectronic series are obtained from the Dirac equation using the B-spline method with Notre Dame boundary conditions. Compact analytic expressions for the polarizabilities as a function of $Z$ with a relative accuracy of 10$^{-6}$ up to $Z = 100$ are determined by fitting to the calculated polarizabilities. The oscillator strengths satisfy the sum rules $\sum_i f^{(\ell)}_{0i} = 0$ for all multipoles from $\ell = 1$ to $\ell = 4$. The dispersion coefficients for the long-range H-H and H-He$^+$ interactions are given.

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