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arxiv: 1209.1108 · v1 · pith:27ZJLISYnew · submitted 2012-09-05 · ❄️ cond-mat.soft · cond-mat.dis-nn

Slow dynamics in cylindrically confined colloidal suspensions

classification ❄️ cond-mat.soft cond-mat.dis-nn
keywords confinedcolloidalglassmoveparticleparticlesslowersuspensions
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We study bidisperse colloidal suspensions confined within glass microcapillary tubes to model the glass transition in confined cylindrical geometries. We use high speed three-dimensional confocal microscopy to observe particle motions for a wide range of volume fractions and tube radii. Holding volume fraction constant, we find that particles move slower in thinner tubes. The tube walls induce a gradient in particle mobility: particles move substantially slower near the walls. This suggests that the confinement-induced glassiness may be due to an interfacial effect.

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