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arxiv: 1209.1620 · v1 · pith:U2KRHW6Rnew · submitted 2012-09-07 · ⚛️ physics.atm-clus

Effect of C₆₀ giant resonance on the photoabsorption of encaged atoms

classification ⚛️ physics.atm-clus
keywords resonanceatomsenergygiantphotoabsorptionencagedinsideabsolute
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The absolute differential oscillator strengths (DOS's) for the photoabsorption of the Ne, Ar, and Xe atoms encapsulated in the C$_{60}$ have been evaluated using the time-dependent-density-functional-theory, which solves the quantum Liouvillian equation with the Lanczos chain method. The calculations are performed in the energy regions both inside and outside the C$_{60}$ giant resonance. The photoabsorption spectra of the atoms encaged in the C$_{60}$ demonstrate strong oscillations inside the energy range of the C$_{60}$ giant resonance. This type of oscillation cannot be explained by the confinement resonance, but is due to the energy transfer from the C$_{60}$ valence electrons to the photoelectron through the intershell coupling.

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