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arxiv: 1307.4238 · v1 · pith:Y6RISAZTnew · submitted 2013-07-16 · 🪐 quant-ph

A variant of the Brillouin-Wigner perturbation theory with Epstein-Nesbet partitioning

classification 🪐 quant-ph
keywords perturbationtheorybrillouin-wignerepstein-nesbetpartitioningvariantaccuracyadvantage
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We present an elementary pedagogical derivation of the Brillouin-Wigner and the Rayleigh-Schr\"odinger perturbation theories with Epstein-Nesbet partitioning. A variant of the Brillouin-Wigner perturbation theory is also introduced, which can be easily extended to the quasi-degenerate case. A main advantage of the new theory is that the computing time required for obtaining the successive higher-order results is negligible after the third-order calculation. We illustrate the accuracy of the new perturbation theory for some simple model systems like the perturbed harmonic oscillator and the particle in a box.

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