Negative area compressibility in silver(I) tricyanomethanide
classification
❄️ cond-mat.mtrl-sci
keywords
areacompressibilitynegativetricyanomethanidearisesbehaviourcollapsecompression
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The molecular framework Ag(tcm) (tcm$^-$ = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.
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