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arxiv: 1403.2008 · v1 · pith:H2OXAMTJnew · submitted 2014-03-08 · ❄️ cond-mat.dis-nn · cond-mat.soft

Excess wing in glass-forming glycerol and LiCl-glycerol mixtures detected by neutron scattering

classification ❄️ cond-mat.dis-nn cond-mat.soft
keywords neutronscatteringexcessglycerolwingdetectedglass-formingrelaxational
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The relaxational dynamics in glass-forming glycerol and glycerol mixed with LiCl is in-vestigated using different neutron scattering techniques. The performed neutron spin-echo experiments, which extend up to relatively long relaxation-time scales of the order of 10 ns, should allow for the detection of contributions from the so-called excess wing. This phenomenon, whose microscopic origin is controversially discussed, arises in a variety of glass formers and, until now, was almost exclusively investigated by dielectric spectros-copy and light scattering. Here we show that the relaxational process causing the excess wing also can be detected by neutron scattering, which directly couples to density fluctua-tions.

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