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arxiv: 1409.4120 · v1 · pith:QEJN34M7new · submitted 2014-09-14 · 🪐 quant-ph

Perturbation theory by the moment method and point-group symmetry

classification 🪐 quant-ph
keywords methodperturbationsymmetryearliermomentpoint-groupsomestates
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We analyze earlier applications of perturbation theory by the moment method (also called inner product method) to anharmonic oscillators. For concreteness we focus on two-dimensional models with symmetry $C_{4v}$ and $C_{2v}$ and reveal the reason why some of those earlier treatments proved unsuitable for the calculation of the perturbation corrections for some excited states. Point-group symmetry enables one to predict which states require special treatment.

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