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arxiv: 1501.00896 · v1 · pith:PQFDOPWNnew · submitted 2015-01-05 · ⚛️ physics.chem-ph

Visible line intensities of the triatomic hydrogen ion from experiment and theory

classification ⚛️ physics.chem-ph
keywords linevisiblecoefficientseinsteinintensitiesstatesactionadvances
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The visible spectrum of H3+ is studied using high-sensitivity action spectroscopy in a cryogenic radiofrequency multipole trap. Advances are made to measure the weak ro-vibrational transitions from the lowest rotational states of H3+ up to high excitation energies providing visible line intensities and, after normalisation to an infrared calibration line, the corresponding Einstein $B$ coefficients. {\it Ab initio} predictions for the Einstein $B$ coefficients are obtained from a highly precise dipole moment surface of H3+ and found to be in excellent agreement, even in the region where states have been classified as chaotic.

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