NMR spin-lattice relaxation in molecular rotor systems
classification
⚛️ physics.chem-ph
keywords
relaxationmolecularratespin-latticeapproachbrownianconfigurationderived
read the original abstract
A general expression is derived for the dipolar NMR spin-lattice relaxation rate $1/T_1$ of a system exhibiting Brownian dynamics in a discrete and finite configuration space. It is shown that this approach can be particularly useful to model the proton relaxation rate in molecular rotors.
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