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arxiv: 1511.03795 · v3 · pith:7K742DFTnew · submitted 2015-11-12 · ❄️ cond-mat.soft

Bundle formation in parallel aligned polymers with competing interactions

classification ❄️ cond-mat.soft
keywords formationbundlepolymerssystemsalignedbundlescompetinginteractions
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Aggregation of like-charged polymers is widely observed in biological and soft matter systems. In many systems, bundles are formed when a short-range attraction of diverse physical origin like charge-bridging, hydrogen-bonding or hydrophobic interaction, overcomes the longer- range charge repulsion. In this Letter, we present a general mechanism of bundle formation in these systems as the breaking of the translational invariance in parallel aligned polymers with competing interactions of this type. We derive a criterion for finite-sized bundle formation as well as for macroscopic phase separation (formation of infinite bundles).

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