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arxiv: 1512.07367 · v2 · pith:EXF32TUMnew · submitted 2015-12-23 · ❄️ cond-mat.quant-gas · physics.atom-ph· quant-ph

Leading gradient correction to the kinetic energy for two-dimensional fermion gases

classification ❄️ cond-mat.quant-gas physics.atom-phquant-ph
keywords energycorrectionfunctionalcorrectionsdensitygradientkineticleading
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Density functional theory (DFT) is notorious for the absence of gradient corrections to the two-dimensional (2D) Thomas-Fermi kinetic-energy functional; it is widely accepted that the 2D analog of the 3D von Weizs\"acker correction vanishes, together with all higher-order corrections. Contrary to this long-held belief, we show that the leading correction to the kinetic energy does not vanish, is unambiguous, and contributes perturbatively to the total energy. This insight emerges naturally in a simple extension of standard DFT, which has the effective potential energy as a functional variable on equal footing with the single-particle density.

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