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arxiv: 1609.07161 · v1 · pith:GTZDLGNAnew · submitted 2016-09-22 · ❄️ cond-mat.mtrl-sci

Crystal structure and low-energy Einstein mode in ErV₂Al₂₀ intermetallic cage compound

classification ❄️ cond-mat.mtrl-sci
keywords measurementseinsteincrystalcurie-weissheatlow-energymagneticmode
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Single crystals of a new ternary aluminide ErV$_2$Al$_{20}$ were grown using a self-flux method. The crystal structure was determined by powder X-ray diffraction measurements and Rietveld refinement, and physical properties were studied by means of electrical resistivity, magnetic susceptibility and specific heat measurements. These measurements reveal that ErV$_2$Al$_{20}$ is a Curie-Weiss paramagnet down to 1.95 K with an effective magnetic moment $\mu_{eff}$ = 9.27(1) $\mu_B$ and Curie-Weiss temperature $\Theta_{CW}$ = -0.55(4) K. The heat capacity measurements show a broad anomaly at low temperatures that is attributed to the presence of a low-energy Einstein mode with characteristic temperature $\Theta_E$ = 44 K, approximately twice as high as in the isostructural 'Einstein solid' VAl$_{10.1}$.

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