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arxiv: 1611.01748 · v3 · pith:LQ4BIHICnew · submitted 2016-11-06 · ❄️ cond-mat.soft

Connection between fragility, mean-squared displacement and shear modulus in two van der Waals bonded glass-forming liquids

classification ❄️ cond-mat.soft
keywords liquidsbondeddependencedisplacementglass-formingmean-squaredmeasuredmodel
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The temperature dependence of the high-frequency shear modulus measured in the kHz range is compared to the mean-squared displacement measured in the nanosecond range for the two van der Waals bonded glass-forming liquids cumene and 5PPE. This provides an experimental test for the assumption connecting two versions of the shoving model for the non-Arrhenius temperature dependence of the relaxation time in glass formers. The two versions of the model are also tested directly and both are shown to work well for these liquids.

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