Solution enthalpies of barium cerates co-doped by rare-earth elements and indium

(2) Karlsruhe Institute of Technology; A.N. Semerikova (1); Germany); Institute of Solid State Physics; I.V. Vyazovkin (1) ((1) Nikolaev Institute of Inorganic Chemistry SB RAS; Karlsruhe; M.Yu. Matskevich (1); N.I. Matskevich (1); O.I. Anyfrieva (1); Th. Wolf (2)

arxiv: 1612.04036 · v1 · pith:VYSX5JRBnew · submitted 2016-12-13 · ❄️ cond-mat.mtrl-sci

Solution enthalpies of barium cerates co-doped by rare-earth elements and indium

N.I. Matskevich (1) , Th. Wolf (2) , A.N. Semerikova (1) , O.I. Anyfrieva (1) , M.Yu. Matskevich (1) , I.V. Vyazovkin (1) ((1) Nikolaev Institute of Inorganic Chemistry SB RAS , (2) Karlsruhe Institute of Technology , Institute of Solid State Physics

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classification ❄️ cond-mat.mtrl-sci

keywords bace0enthalpiesdissolutiondatameasuredsolutionwereacid

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The dissolution enthalpies of BaCe0.7Ho0.2In0.1O2.85 and BaCe0.7Sm0.2In0.1O2.85 were measured by method of solution calorimetry in 1M hydrochloric acid with adding 0.1 M KI. The obtained data were compared with earlier measured data on dissolution enthalpies of BaCe0.7Nd0.2In0.1O2.85, BaCe0.7Gd0.2In0.1O2.85. The dependence of dissolution enthalpies from lanthanide radius was constructed. As was shown the relationship is not linear.

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Solution enthalpies of barium cerates co-doped by rare-earth elements and indium

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