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arxiv: 1704.03038 · v1 · pith:RG75YPPJnew · submitted 2017-04-10 · ❄️ cond-mat.mtrl-sci

Cubine, a superconducting 2-dimensional copper-bismuth nano sheet

classification ❄️ cond-mat.mtrl-sci
keywords cubinecalculationscopper-bismuthdimensionallayersmaterialnanosheet
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We report on the discovery of a 2-dimensional copper-bismuth nano sheet from \textit{ab initio} calculations, which we call cubine. According to our predictions, single layers of cubine can be isolated from the recently reported high-pressure CuBi bulk material (metastable at ambient conditions) at an energetic cost of merely $\approx 20$~meV/\AA$^2$, comparable to separating single layers of graphene from graphite. Our calculations suggest that cubine has remarkable electronic and electrochemical properties: It is a superconductor with a moderate electron-phonon coupling $\lambda=0.5$, leading to a $T_c$ of $\approx1$~K, and can be readily intercalated with lithium with a high diffusibility, rendering it a promising candidate material as an anode in lithium-ion batteries.

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