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Magnetic, transport, and thermal properties of $\delta$-phase UZr$_2$

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arxiv 2008.02746 v1 pith:GP7BRCGH submitted 2020-08-06 cond-mat.str-el cond-mat.mtrl-scicond-mat.other

classification cond-mat.str-elcond-mat.mtrl-scicond-mat.other
keywords magneticdeltabeendisorderelectricalmagnetoresistancephaseresistivity
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abstract

Alloys of hexagonal $\delta$-phase UZr$_2$ have been synthesized and studied by means of heat capacity, magnetic susceptibility, magnetization, electrical resistivity, magnetoresistance, thermoelectric power, thermal conductivity measurements, for the first time, at temperatures from 1.8 to 300 K and in magnetic fields up to 8 T. The weak temperature dependence of the magnetic susceptibility and the small value of both Seebeck (0.75 $\mu$V/K at room temperature) and of the Sommerfeld coefficient (13.5 mJ mol$^{-1}$ K$^{-2}$) point to 5$f$-electrons in this material having a delocalized nature. The electrical resistivity and magnetoresistance indicate the presence of significant electronic disorder in $\delta$-UZr$_2$, consistent with the disorder in its crystal structure. Density functional theory calculations have been performed and compared to experimental results.

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