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arxiv: 2008.02892 · v2 · pith:Z3EQSUFZnew · submitted 2020-08-06 · ⚛️ physics.app-ph · cond-mat.mtrl-sci

Comment on "Resolving spatial and energetic distributions of trap states in metal halide perovskite solar cells"

classification ⚛️ physics.app-ph cond-mat.mtrl-sci
keywords densitiestrapperovskitebulkcapacitancechargehalideinterfacial
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Ni et al. report minimum bulk trap densities of 10^11 cm-3 and 1-4 orders change in interfacial trap densities derived from drive-level capacitance profiling of lead halide perovskites. From basic electrostatic arguments, we show that such bulk trap densities cannot be resolved for a p-i-n perovskite solar cell for the reported layer thicknesses, while the apparent interfacial charge densities are a consequence of the geometrical capacitance and of charge injection into the perovskite layer.

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