Tunable Magnetic Skyrmions in Ferrimagnetic Mn₄N

Thin films of ferrimagnetic Mn$_4$N are candidate materials to host magnetic skyrmions that have demonstrated thermal stability up to 450$^\circ$C. However, there are no experimental reports observing skyrmions in this system. Here, we discuss the results of sputter grown 15-17~nm Mn$_4$N thin films on MgO substrate capped with Pt$_{1-x}$Cu$_{x}$ layers. Vibrating sample magnetometry measurement of out-of-plane hysteresis loops confirmed that magnetic properties are insensitive to the cap layer composition. Imaging based on magnetic force microscopy measurements observed 300 to 50~nm sized skyrmions, as the Cu concentration was increased from $x$ = 0 to 0.9. We performed density functional theory calculations and found that the interfacial Dzyaloshinskii-Moriya interactions (iDMI) follow a trend: Mn$_4$N/MgO(001) $<$ Cu/Mn$_4$N(001) $<$ Pt/Mn$_4$N(001). We infer from these calculations that $x$ in Pt$_{1-x}$Cu$_{x}$ capping layer can serve as a robust tuning knob to tailor the iDMI and control the skyrmion size. This work provides guidance to achieve smaller N\'{e}el-type skyrmions in Mn$_4$N thin films, which is an important step forward for building thermally stable skyrmionic devices.