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Diffusion coefficient power laws and defect-driven glassy dynamics in swap acceleration

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arxiv 2111.11697 v2 pith:X4V5AUQG submitted 2021-11-23 cond-mat.dis-nn cond-mat.soft

classification cond-mat.dis-nncond-mat.soft
keywords dynamicsparticlesglassglassydefectdiffusionlawsparticle
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Particle swaps can drastically accelerate dynamics in glass. The mechanism is expected to be vital for a fundamental understanding of glassy dynamics. To extract defining features, we propose a partial swappability with a fraction {\phi_s} of swap-initiating particles, which can only swap locally with each other or with regular particles. We focus on the swap-dominating regime. At all temperatures studied, particle diffusion coefficients scale with {\phi_s} in unexpected power laws with temperature-dependent exponents, consistent with the kinetic picture of glass transition. At small {\phi_s}, swap-initiators, becoming defect particles, induce remarkably typical glassy dynamics of regular particles. This supports defect models of glass.

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