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Let $\mathfrak{S}_n$ denote the symmetric group and let $W(\mathfrak{S}_n)$ denote the weak order of $\mathfrak{S}_n$. Through a surprising connection to a subset of parking functions, which we call unit Fubini rankings, we provide a complete characterization and enumeration for the total number of Boolean intervals in $W(\mathfrak{S}_n)$ and the total number of Boolean intervals of rank $k$ in $W(\mathfrak{S}_n)$. Furthermore, for any $\pi\in\mathfrak{S}_n$, we establish that the number of Boolean intervals in $W(\mathfrak{S}_n)$ with minimal element $\pi$ is a product of Fibonacci numbers. We conclude with some directions for further study.