Infrared Compositional Measurements in Comet C/2017 K2 (Pan-STARRS) at Heliocentric Distances Beyond 2.3 AU

Comet C/2017 K2 (Pan-STARRS) provided a rare opportunity to investigate the evolution of coma composition and outgassing patterns over a transitional heliocentric distance (Rh) range where activity drivers in comets are thought to change from "hypervolatile" (CO, CH$_4$, C$_2$H$_6$, and/or CO$_2$)-dominated to H2O-dominated. We performed high-resolution, cross-dispersed, near-infrared spectroscopy of C/2017 K2 with iSHELL at the NASA Infrared Telescope Facility (IRTF) and NIRSPEC at the W. M. Keck 2 Observatory. We report gas rotational temperatures (Trot) and molecular production rates (Q; mol/s) or upper limits for the hypervolatile species CH$_4$, CO, and C$_2$H$_6$, together with less volatile ices (CH$_3$OH, H$_2$O, HCN, C$_2$H$_2$, NH$_3$, and OCS) over a range of pre-perihelion distances, Rh= 3.15 - 2.35 au. We also report (or stringently constrain) abundance ratios (mixing ratios) of the targeted species with respect to CO, C$_2$H$_6$, and (when detected) H$_2$O. All volatiles were enriched relative to water in C/2017 K2 when compared to their mean values among Oort Cloud comets, whereas abundances relative to C2H6 were consistent with their average values from other long-period comets.