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Experimental demonstration of Robust Amplitude Estimation on near-term quantum devices for chemistry applications

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arxiv 2410.00686 v1 pith:ONJ7RL5Q submitted 2024-10-01 quant-ph

classification quant-ph
keywords quantumchemistryhardwareaccuracyachievedamplitudeapplicationscomputational
verification ladder T0 review T1 audit T2 compute T3 formal

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This study explores hardware implementation of Robust Amplitude Estimation (RAE) on IBM quantum devices, demonstrating its application in quantum chemistry for one- and two-qubit Hamiltonian systems. Known for potentially offering quadratic speedups over traditional methods in estimating expectation values, RAE is evaluated under realistic noisy conditions. Our experiments provide detailed insights into the practical challenges associated with RAE. We achieved a significant reduction in sampling requirements compared to direct measurement techniques. In estimating the ground state energy of the hydrogen molecule, the RAE implementation demonstrated two orders of magnitude better accuracy for the two-qubit experiments and achieved chemical accuracy. These findings reveal its potential to enhance computational efficiencies in quantum chemistry applications despite the inherent limitations posed by hardware noise. We also found that its performance can be adversely impacted by coherent error and device stability and does not always correlate with the average gate error. These results underscore the importance of adapting quantum computational methods to hardware specifics to realize their full potential in practical scenarios.

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Cited by 1 Pith paper

Reviewed papers in the Pith corpus that reference this work. Sorted by Pith novelty score. Full citation record

  1. Quantum Measurement for Quantum Chemistry on a Quantum Computer

    quant-ph 2025-01 accept novelty 3.0 of 10

    This review organizes quantum measurement techniques for quantum chemistry into three cost categories: VQE-era Hamiltonian partitioning, classical shadows, POVM-based schemes, and quantum phase estimation inspired met...

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