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arxiv: 2411.18890 · v2 · submitted 2024-11-28 · 🪐 quant-ph · physics.atom-ph

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How Are Quantum Eigenfunctions of Hydrogen Atom Related To Its Classical Elliptic Orbits?

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classification 🪐 quant-ph physics.atom-ph
keywords classicalorbitsenergyquantumangularatomdistributionelliptic
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We show that a highly-excited energy eigenfunction $\psi_{nlm}(\vec{r})$ of hydrogen atom can be approximated as an equal-weight superposition of classical elliptic orbits with energy $E_n$ and angular momentum $L=\sqrt{l(l+1)}\hbar$, and $z$ component of angular momentum $L_z=m\hbar$. This correspondence is established by comparing the quantum probability distribution $|\psi_{nlm}(\vec{r})|^2$ and the classical probability distribution $p_c(\vec{r})$ of an ensemble of such orbits. This finding illustrates a general principle: in the semi-classical limit, an energy eigenstate of a quantum system is in general reduced to a collection of classical orbits, rather than a single classical orbit.

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