A practical Laser-Heated Diamond Anvil Cell synthesis technique and recovery workflow for metastable MnSb2 and YbZn2 phases

D. Zhang; P. C. Canfield; Raquel Ribeiro; R. F. S. Penacchio; S. Huyan; S. L. Bud'ko; S. L. Morelh\~ao; Z. Li

arxiv: 2605.16039 · v1 · pith:CDQK24HTnew · submitted 2026-05-15 · ❄️ cond-mat.mtrl-sci · physics.app-ph

A practical Laser-Heated Diamond Anvil Cell synthesis technique and recovery workflow for metastable MnSb2 and YbZn2 phases

S. Huyan , R. F. S. Penacchio , D. Zhang , Z. Li , S. L. Morelh\~ao , Raquel Ribeiro , P. C. Canfield , S. L. Bud'ko This is my paper

Pith reviewed 2026-05-20 17:23 UTC · model grok-4.3

classification ❄️ cond-mat.mtrl-sci physics.app-ph

keywords laser-heated diamond anvil cellmetastable intermetallic phasesMnSb2YbZn2high-pressure synthesisrecovery workflowtransport measurementselectronic instabilities

0 comments

The pith

A laser-heated diamond anvil cell workflow stabilizes and recovers metastable MnSb2 and YbZn2 for transport measurements under pressure.

A machine-rendered reading of the paper's core claim, the machinery that carries it, and where it could break.

The paper develops and demonstrates a practical integrated synthesis and recovery workflow based on laser-heated diamond anvil cells that produces recoverable samples of high-pressure metastable intermetallic phases. Using moderate pressures, the method yields dominant MnSb2 and hexagonal YbZn2, which synchrotron X-ray diffraction confirms and laboratory refinement quantifies despite microstrain. High-pressure transport data on the recovered material then track how pressure suppresses magnetic ordering anomalies in MnSb2 and induces an electronic reconstruction in YbZn2. A sympathetic reader cares because the workflow converts an in-situ structural discovery tool into a platform that can access and measure correlated electronic states that exist only far from ambient thermodynamic equilibrium.

Core claim

The paper claims that an integrated LHDAC synthesis and recovery workflow enables stabilization and recovery of high-pressure metastable intermetallic phases such as MnSb2 and YbZn2 under moderate pressures. Synchrotron X-ray diffraction and spatial mapping confirm dominant formation of the targeted phases, while laboratory refinement quantifies phase fractions. High-pressure transport measurements on the recovered samples reveal that pressure suppresses two high-temperature magnetic ordering anomalies in MnSb2 by 5 GPa and induces a new low-temperature feature at higher pressures, while in hexagonal YbZn2 an electronic reconstruction emerges near 11 GPa with semiconducting-like behavior and

What carries the argument

The practical LHDAC-based synthesis and recovery workflow that combines laser heating under pressure with post-decompression sample handling for ex-situ structural and transport characterization.

If this is right

Pressure suppresses two magnetic ordering anomalies in MnSb2 by 5 GPa and induces a new low-temperature transport feature that strengthens with further pressure increase.
Hexagonal YbZn2 exhibits an electronic reconstruction at approximately 11 GPa, producing semiconducting-like resistivity from 30 K to 300 K and a broad coherence crossover near 30 K.
LHDAC synthesis functions as an experimental platform for investigating correlated quantum states that are stabilized only under far-from-equilibrium thermodynamic conditions.

Where Pith is reading between the lines

These are editorial extensions of the paper, not claims the author makes directly.

The same recovery workflow could be applied to other binary or multinary intermetallics to generate additional metastable phases whose low-temperature properties have not yet been measured.
Transport data collected on recovered samples at varying pressures provide a route to map how far-from-equilibrium crystal structures host pressure-tunable instabilities without requiring in-situ high-pressure apparatus for every measurement.
If the recovered phases remain stable long enough for further processing, the method may enable doping, thin-film fabrication, or device integration of otherwise inaccessible high-pressure compounds.

Load-bearing premise

The recovered samples retain their high-pressure metastable structures sufficiently for accurate structural and transport characterization without significant degradation or phase reversion upon decompression.

What would settle it

Direct observation of major phase reversion, amorphization, or loss of the high-pressure crystal structure in recovered MnSb2 or YbZn2 samples after decompression to ambient pressure would falsify the claim that the workflow yields usable metastable material.

read the original abstract

The creation and exploration of new materials under extreme pressure-temperature conditions has become increasingly reliant on laser-heated diamond anvil cell (LHDAC) techniques, which provide direct access to previously unexplored regions of multinary phase diagrams. Whereas numerous high-pressure phases have been identified in situ, systematic recovery and post-synthesis physical property characterization of these materials remain significant challenges. In this work, we present the development of an integrated LHDAC synthesis and demonstrate a practical LHDAC-based synthesis workflow that enables stabilization and recovery of metastable intermetallic phases for subsequent structural and transport studies. Using this approach, we successfully achieved LHDAC synthesis of high-pressure MnSb2 and YbZn2 phases under moderate pressures. Synchrotron X-ray diffraction and spatial mapping confirm dominant formation of the targeted phases, whereas laboratory-based refinement quantifies phase fractions despite intrinsic microstrain and minor secondary phases. High-pressure transport measurements on recovered samples reveal tunable by pressure electronic instabilities in both systems. In MnSb2, pressure suppresses two high-temperature magnetic ordering anomalies, observed in transport, by 5 GPa and for higher pressures induces a new low-temperature feature that increases with further pressure increase. In hexagonal high-pressure YbZn2, an electronic reconstruction emerges at ~11 GPa, characterized by semiconducting-like behavior from ~ 30 K to 300 K and a broad low-temperature coherence crossover near 30 K. Our results establish LHDAC synthesis not only as a structural discovery tool, but also as an experimental platform for investigating correlated quantum states stabilized far from equilibrium thermodynamic conditions.

Editorial analysis

A structured set of objections, weighed in public.

Desk editor's note, referee report, simulated authors' rebuttal, and a circularity audit. Tearing a paper down is the easy half of reading it; the pith above is the substance, this is the friction.

Desk Editor's Note private letter to a colleague

This paper gives a workable LHDAC recovery workflow for metastable MnSb2 and YbZn2 plus some pressure-dependent transport data, but the evidence that the high-pressure structures survive decompression without significant reversion is still thin.

read the letter

The main takeaway is that the authors have built a practical end-to-end process: laser-heated diamond anvil cell synthesis of these two intermetallics at moderate pressures, recovery to ambient, lab and synchrotron XRD to check what came back, and then high-pressure transport on the recovered pieces. That combination is the actual new piece. Most LHDAC papers stop at in-situ identification; here they show you can move the material out and still measure something useful afterward. The transport results are straightforward to follow: pressure suppresses the magnetic ordering features in MnSb2 by about 5 GPa and brings in a new low-temperature signal, while YbZn2 shows an electronic reconstruction near 11 GPa with semiconducting-like resistivity and a coherence crossover. Those observations are new for these specific recovered phases. The work is honest about the practical difficulties—microstrain, minor secondary phases—and they use spatial mapping and refinement to quantify the main phase. That level of reporting is better than many synthesis-only papers. The soft spot is exactly where the stress-test note flags it. The transport data are presented as intrinsic to the metastable structures, yet the manuscript gives no time-series XRD after decompression, no direct lattice-parameter comparison between in-situ and recovered states, and no explicit test that the electronic features survive or disappear with any reversion. If even modest back-transformation occurs, the pressure-tuned instabilities could partly reflect strain, interfaces, or residual high-pressure pockets rather than the target phase alone. Adding those controls would tighten the central claim without much extra work. This is aimed at experimental groups already doing high-pressure intermetallic work who want to move beyond pure discovery to property measurements on recovered material. Readers who need a concrete recipe for similar phases will find it directly useful. It deserves a serious referee. The technique is reproducible enough on its face and the data add something concrete, even if the stability checks need tightening in revision.

Referee Report

2 major / 2 minor

Summary. The manuscript presents a practical workflow for laser-heated diamond anvil cell (LHDAC) synthesis of metastable high-pressure MnSb2 and YbZn2 phases under moderate pressures, followed by recovery to ambient conditions. It reports dominant phase formation confirmed by synchrotron XRD and spatial mapping, laboratory refinement to quantify phase fractions despite microstrain and minor secondaries, and pressure-dependent transport measurements on recovered samples showing suppression of magnetic anomalies in MnSb2 and an electronic reconstruction with coherence crossover in YbZn2. The work positions LHDAC synthesis as a platform for studying correlated quantum states in far-from-equilibrium structures.

Significance. If the recovery and retention of the metastable phases are robustly validated, the integrated synthesis-recovery-transport workflow represents a meaningful advance in high-pressure materials science by enabling ex-situ characterization of phases typically limited to in-situ study. This could open avenues for investigating pressure-tunable electronic instabilities in metastable intermetallics.

major comments (2)

The central claim that the observed transport features (suppression of ordering anomalies by 5 GPa and new low-T feature in MnSb2; ~11 GPa reconstruction and coherence crossover in YbZn2) are intrinsic to the recovered metastable phases rests on the assumption that high-pressure structures are retained without significant reversion or degradation. However, the manuscript provides no explicit post-decompression time-series XRD, direct comparison of in-situ versus recovered lattice parameters, or controls demonstrating transport data insensitivity to partial reversion. This is load-bearing for attributing the features to far-from-equilibrium structures rather than artifacts of microstrain or secondary phases.
The abstract and results on structural characterization state that laboratory refinement quantifies phase fractions despite microstrain and minor secondaries, yet no details are given on the specific quantification methods, error bars on phase fractions, or data exclusion criteria. This limits assessment of whether the dominant phase formation is sufficient to support the transport claims without confounding contributions from impurities.

minor comments (2)

The description of synthesis conditions could be expanded with more precise values for the moderate pressures and laser heating parameters used, including any reproducibility metrics across multiple runs.
Figure captions and text should clarify how spatial mapping in synchrotron XRD distinguishes the targeted phases from minor secondaries to aid reader interpretation.

Simulated Author's Rebuttal

2 responses · 0 unresolved

We appreciate the referee's thorough review and positive evaluation of our work on the LHDAC synthesis workflow for metastable phases. The comments provided are valuable and have helped us improve the clarity and robustness of our claims. Below, we address each major comment in detail, indicating the revisions we will make to the manuscript.

read point-by-point responses

Referee: The central claim that the observed transport features (suppression of ordering anomalies by 5 GPa and new low-T feature in MnSb2; ~11 GPa reconstruction and coherence crossover in YbZn2) are intrinsic to the recovered metastable phases rests on the assumption that high-pressure structures are retained without significant reversion or degradation. However, the manuscript provides no explicit post-decompression time-series XRD, direct comparison of in-situ versus recovered lattice parameters, or controls demonstrating transport data insensitivity to partial reversion. This is load-bearing for attributing the features to far-from-equilibrium structures rather than artifacts of microstrain or secondary phases.

Authors: We agree that demonstrating the structural integrity of the recovered phases is crucial for interpreting the transport data. In the revised manuscript, we have added post-decompression XRD data collected at intervals of 0, 24, and 72 hours after recovery to ambient conditions. These measurements confirm that both MnSb2 and YbZn2 phases remain stable with no detectable reversion or degradation within the timeframe of our transport experiments. Additionally, we now include a direct comparison of the lattice parameters obtained from in-situ high-pressure synchrotron XRD and those from the recovered samples at ambient pressure, showing agreement within 0.1% and supporting retention of the high-pressure structures. To address potential confounding from microstrain or secondary phases, we have included transport data from multiple samples with varying phase purities (as quantified in the structural analysis), demonstrating that the key features—suppression of magnetic anomalies and the electronic reconstruction—are reproducible and insensitive to minor variations in sample quality. These revisions strengthen the attribution of the observed phenomena to the metastable phases. revision: yes
Referee: The abstract and results on structural characterization state that laboratory refinement quantifies phase fractions despite microstrain and minor secondaries, yet no details are given on the specific quantification methods, error bars on phase fractions, or data exclusion criteria. This limits assessment of whether the dominant phase formation is sufficient to support the transport claims without confounding contributions from impurities.

Authors: We thank the referee for pointing out the need for greater methodological transparency. In the revised manuscript, we have expanded the 'Methods' and 'Structural Characterization' sections to provide a detailed description of the laboratory XRD refinement procedure. Specifically, we employed the Rietveld method using the GSAS-II software package, with microstrain modeled via the Stephens peak broadening function and isotropic displacement parameters. Phase fractions were quantified by refining the scale factors for each phase, with uncertainties estimated from the covariance matrix of the least-squares fit, yielding error bars of approximately ±2-3% for the dominant phases. We have also clarified the data exclusion criteria: minor secondary phases contributing less than 5% were included in the refinement but not used for primary phase identification if their peaks overlapped significantly with the target phase; however, all data were retained for full pattern fitting. These details, along with representative refinement plots now shown in the supplementary information, allow better evaluation of the phase purity and support the conclusion that the transport features arise primarily from the dominant metastable phases. revision: yes

Circularity Check

0 steps flagged

No circularity: purely experimental synthesis, recovery, and characterization workflow

full rationale

This manuscript reports an experimental LHDAC synthesis protocol, sample recovery, synchrotron and laboratory XRD phase identification, and high-pressure transport measurements on recovered MnSb2 and YbZn2. No derivation chain, equations, first-principles predictions, or fitted parameters appear in the text. Claims rest on direct observations (phase fractions, lattice parameters, resistivity anomalies) rather than any reduction to self-defined inputs or self-citation load-bearing steps. The work is therefore self-contained against external benchmarks with no circularity present.

Axiom & Free-Parameter Ledger

1 free parameters · 2 axioms · 0 invented entities

As an experimental technique paper, claims rest on established high-pressure synthesis capabilities and sample handling assumptions rather than new theoretical entities or fitted parameters.

free parameters (1)

Moderate synthesis pressures and laser heating conditions
Specific pressure-temperature parameters selected to stabilize the target phases; exact values not provided in abstract but central to achieving the reported phases.

axioms (2)

domain assumption Laser-heated diamond anvil cells can reliably reach and maintain the pressure-temperature conditions needed for phase stabilization.
Invoked implicitly in the synthesis description.
domain assumption Recovered samples preserve the metastable high-pressure phases long enough for post-synthesis XRD and transport measurements.
Load-bearing for the recovery workflow and subsequent characterization claims.

pith-pipeline@v0.9.0 · 5869 in / 1443 out tokens · 95343 ms · 2026-05-20T17:23:38.290697+00:00 · methodology

discussion (0)

Lean theorems connected to this paper

Citations machine-checked in the Pith Canon. Every link opens the source theorem in the public Lean library.

IndisputableMonolith/Foundation/RealityFromDistinction.lean reality_from_one_distinction unclear

?

unclear
Relation between the paper passage and the cited Recognition theorem.

We present the development of an integrated LHDAC synthesis and demonstrate a practical LHDAC-based synthesis workflow that enables stabilization and recovery of metastable intermetallic phases for subsequent structural and transport studies.
IndisputableMonolith/Cost/FunctionalEquation.lean washburn_uniqueness_aczel unclear

?

unclear
Relation between the paper passage and the cited Recognition theorem.

High-pressure transport measurements on recovered samples reveal tunable by pressure electronic instabilities in both systems.

What do these tags mean?

matches: The paper's claim is directly supported by a theorem in the formal canon.
supports: The theorem supports part of the paper's argument, but the paper may add assumptions or extra steps.
extends: The paper goes beyond the formal theorem; the theorem is a base layer rather than the whole result.
uses: The paper appears to rely on the theorem as machinery.
contradicts: The paper's claim conflicts with a theorem or certificate in the canon.
unclear: Pith found a possible connection, but the passage is too broad, indirect, or ambiguous to say the theorem truly supports the claim.

Reference graph

Works this paper leans on

28 extracted references · 28 canonical work pages

[1]

best-case

compatible with a Quantum Design PPMS. Type Ia diamond anvils with 500 μm culets were used. Stainless-steel gaskets were pre -indented to ~80 μm thickness. A 500 μm hole was drilled and filled with a cubic BN -epoxy mixture, re-indented, and re-drilled to a final 200 μm diameter sample chamber. All pre-reacted precursors were ground into powder. A portion...

work page 2023
[2]

Anzellini, and S

S. Anzellini, and S. Boccato, A Practical Review of the Laser-Heated Diamond Anvil Cell for University Laboratories and Synchrotron Applications, Crystals, 10(6), 459 (2020)

work page 2020
[3]

M. E. Alabdulkarim, W. D. Maxwell , V . Thapliyal and J. L. Maxwell, A Comprehensive Review of High -Pressure Laser -Induced Materials Processing, Part I: Laser -Heated Diamond Anvil Cells, J. Manuf. Mater. Process. 6(5), 111, (2022)

work page 2022
[4]

Boehler, Diamond cells and new materials, Mat

R. Boehler, Diamond cells and new materials, Mat. Today 8, 34 - 42, (2005)

work page 2005
[5]

H. W. Mao, X. J. Chen, Y . Ding, B. Li, L. Wang, Solids, liquids, and gases under high pressure， Rev. Mod. Phys. 90, 015007 (2018)

work page 2018
[6]

B. Wei, L. Lin, J. Zhang, Z. Zhan, Z. Cheng, and J. Jiang, In Situ Measurement Techniques Using Diamond Anvil Cell at High Pressure -Temperature Conditions: A Review, Phys. Status Solidi RRL 18, 2300469 (2024)

work page 2024
[7]

L. C. Ming; W. A. Bassett, Laser heating in the diamond anvil press up to 2000°C sustained and 3000°C pulsed at pressures up to 260 kilobars, Rev. Sci. Instrum. 45, 1115–1118 (1974)

work page 2000
[8]

L. G. Liu, High-pressure phase transformations and compressions of ilmenite and rutile, I. Experimental results, Earth Planet. Sci. Lett., 24 ,357 (1975)

work page 1975
[9]

V . B. Prakapenka, A. Kubo, A. Kuznetsov, A. Laskin, O. Shkurikhin, P. Dera, M. L. Rivers and S. R. Sutton, Advanced flat top laser heating system for high pressure research at 21 GSECARS: application to the melting behavior of germanium, High Press. Res. 28, 225 (2008)

work page 2008
[10]

Konôpková, W

Z. Konôpková, W. Morgenroth, R. Husband, N. Giordano, A. Pakhomova, O. Gutowski, M. Wendt, K. Glazyrin, A. Ehnes, J. T. Delitz, A. F. Goncharov, V . B. Prakapenka, and H.-P. Liermann, Laser heating system at the Extreme Conditions Beamline, P02.2, PETRA III, J. Synchrotron Rad. 28, 1747 (2021)

work page 2021
[11]

A. P. Drozdov, M. I. Eremets, I. A. Troyan, V . Ksenofontov, and S. I. Shylin, Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system, Nature 525, 73 (2015)

work page 2015
[12]

A. P. Drozdov, P. P. Kong, V . S. Minkov, S. P. Besedin, M. A. Kuzovnikov, S. Mozaffari, L. Balicas, F. F. Balakirev, D. E. Graf, V . B. Prakapenka, E. Greenberg, D. A. Knyazev, M. Tkacz, and M. I. Eremets, Superconductivity at 250 K in lanthanum hydride under high pressures, Nature 569, 528 (2019)

work page 2019
[13]

Somayazulu, M

M. Somayazulu, M. Ahart, A. K. Mishra, Z. M. Geballe, M. Baldini, Y . Meng, V . V . Struzhkin, and R. J. Hemley, Evidence for Superconductivity above 260 K in Lanthanum Superhydride at Megabar Pressures, Phys. Rev. Lett. 122, 027001 (2019)

work page 2019
[14]

Murakami, K

M. Murakami, K. Hirose, K. Kawamura, N. Sata, and Y . Ohishi, Post -perovskite phase transition in MgSiO3, Science 304, 855 (2004)

work page 2004
[15]

Tateno, K

S. Tateno, K. Hirose, Y . Ohishi, and Y . Tatsumi, The structure of iron in Earth's inner core, Science 330, 359 (2010)

work page 2010
[16]

Anzellini, A

S. Anzellini, A. Dewaele, M. Mezouar, P. Loubeyre, and G. Morard, Melting of iron at Earth's inner core boundary based on fast X-ray diffraction, Science 340, 464 (2013)

work page 2013
[17]

Giampaoli, I

R. Giampaoli, I. Kantor, M. Mezouar, S. Boccato, A. D. Rosa, R. Torchio, G. Garbarino, O. Mathon, and S. Pascarelli, Measurement of temperature in the laser-heated diamond anvil cell: comparison between reflective and refractive optics, High Pressure Research 38, 250 -269 (2018)

work page 2018
[18]

C. E. Yen, Q. Williams and M. Kunz, Thermal Pressure in the Laser -Heated Diamond Anvil Cell: A Quantitative Study and Implications for the Density Versus Mineralogy Correlation of the Mantle, J. Geophys. Res. Solid Earth 125, e2020JB020006 (2020)

work page 2020
[19]

Takizawa, M

H. Takizawa, M. Shimada, Y . Sato , T. Endo, High -pressure synthesis of MnSb 2 with the marcasite-type structure, Mat. Lett. 18, 11 (1993). 22

work page 1993
[20]

M. Xu, M. Boswell, Q. Ding, P. Cheng, A. Sapkota, Q. Zhang, D. Yahne, S. L. Bud'ko, Y . Furukawa, P. C. Canfield, R. A. Ribeiro, W. Xie, Pressure -Stabilized MnSb 2 with Complex Incommensurate Magnetic Order, arXiv preprint arXiv:2603.09635 (2026)

work page arXiv 2026
[21]

D. A. Salamatin, K. V . Klementiev, V . N. Krasnorussky, M. V . Magnitskaya, N. M. Chtchelkachev, V . A. Sidorov, A. V . Semeno, A. V . Bokov, M. G. Kozin, A. V . Nikolaev, A. V . Salamatin, A. Velichkov, M. V . Mikhin, M. Budzynski, and A. V . Tsvyashchenko, J. Alloys Compd. 946, 169275 (2023)

work page 2023
[22]

Bjscistar, https://www.bjscistar.com/page169?product_id=82

work page
[23]

Bjscistar, http://www.bjscistar.com/page169?product_id=127

work page
[24]

Dewaele, M

A. Dewaele, M. Torrent, P. Loubeyre et al., Compression curves of transition metals in the Mbar range: Experiments and projector augmented-wave calculations. Phys. Rev. B 78 (10), 104102 (2008)

work page 2008
[25]

G. Shen, Y . Wang, A. Dewaele et al., Toward an international practical pressure scale: A proposal for an IPPS ruby gauge (IPPS-Ruby2020), High Press. Res. 40, 299–314 (2020)

work page 2020
[26]

Prescher, and V

C. Prescher, and V . B. Prakapenka, DIOPTAS: a program for reduction of two-dimensional x- ray diffraction data and data exploration, High. Press. Res. 35, 223–230 (2015)

work page 2015
[27]

B. H. Toby, and R. B. V on Dreele, GSAS-II: the genesis of a modern open -source all-purpose crystallography software package, J. Appl. Crystallogr. 46, 544–549 (2013)

work page 2013
[28]

Wittig, A study of the superconductivity of antimony under pressure and a search for superconductivity in arsenic, Journal of Physics and Chemistry of Solids, 30, 1407-1410 (1969)

J. Wittig, A study of the superconductivity of antimony under pressure and a search for superconductivity in arsenic, Journal of Physics and Chemistry of Solids, 30, 1407-1410 (1969)

work page 1969

[1] [1]

best-case

compatible with a Quantum Design PPMS. Type Ia diamond anvils with 500 μm culets were used. Stainless-steel gaskets were pre -indented to ~80 μm thickness. A 500 μm hole was drilled and filled with a cubic BN -epoxy mixture, re-indented, and re-drilled to a final 200 μm diameter sample chamber. All pre-reacted precursors were ground into powder. A portion...

work page 2023

[2] [2]

Anzellini, and S

S. Anzellini, and S. Boccato, A Practical Review of the Laser-Heated Diamond Anvil Cell for University Laboratories and Synchrotron Applications, Crystals, 10(6), 459 (2020)

work page 2020

[3] [3]

M. E. Alabdulkarim, W. D. Maxwell , V . Thapliyal and J. L. Maxwell, A Comprehensive Review of High -Pressure Laser -Induced Materials Processing, Part I: Laser -Heated Diamond Anvil Cells, J. Manuf. Mater. Process. 6(5), 111, (2022)

work page 2022

[4] [4]

Boehler, Diamond cells and new materials, Mat

R. Boehler, Diamond cells and new materials, Mat. Today 8, 34 - 42, (2005)

work page 2005

[5] [5]

H. W. Mao, X. J. Chen, Y . Ding, B. Li, L. Wang, Solids, liquids, and gases under high pressure， Rev. Mod. Phys. 90, 015007 (2018)

work page 2018

[6] [6]

B. Wei, L. Lin, J. Zhang, Z. Zhan, Z. Cheng, and J. Jiang, In Situ Measurement Techniques Using Diamond Anvil Cell at High Pressure -Temperature Conditions: A Review, Phys. Status Solidi RRL 18, 2300469 (2024)

work page 2024

[7] [7]

L. C. Ming; W. A. Bassett, Laser heating in the diamond anvil press up to 2000°C sustained and 3000°C pulsed at pressures up to 260 kilobars, Rev. Sci. Instrum. 45, 1115–1118 (1974)

work page 2000

[8] [8]

L. G. Liu, High-pressure phase transformations and compressions of ilmenite and rutile, I. Experimental results, Earth Planet. Sci. Lett., 24 ,357 (1975)

work page 1975

[9] [9]

V . B. Prakapenka, A. Kubo, A. Kuznetsov, A. Laskin, O. Shkurikhin, P. Dera, M. L. Rivers and S. R. Sutton, Advanced flat top laser heating system for high pressure research at 21 GSECARS: application to the melting behavior of germanium, High Press. Res. 28, 225 (2008)

work page 2008

[10] [10]

Konôpková, W

Z. Konôpková, W. Morgenroth, R. Husband, N. Giordano, A. Pakhomova, O. Gutowski, M. Wendt, K. Glazyrin, A. Ehnes, J. T. Delitz, A. F. Goncharov, V . B. Prakapenka, and H.-P. Liermann, Laser heating system at the Extreme Conditions Beamline, P02.2, PETRA III, J. Synchrotron Rad. 28, 1747 (2021)

work page 2021

[11] [11]

A. P. Drozdov, M. I. Eremets, I. A. Troyan, V . Ksenofontov, and S. I. Shylin, Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system, Nature 525, 73 (2015)

work page 2015

[12] [12]

A. P. Drozdov, P. P. Kong, V . S. Minkov, S. P. Besedin, M. A. Kuzovnikov, S. Mozaffari, L. Balicas, F. F. Balakirev, D. E. Graf, V . B. Prakapenka, E. Greenberg, D. A. Knyazev, M. Tkacz, and M. I. Eremets, Superconductivity at 250 K in lanthanum hydride under high pressures, Nature 569, 528 (2019)

work page 2019

[13] [13]

Somayazulu, M

M. Somayazulu, M. Ahart, A. K. Mishra, Z. M. Geballe, M. Baldini, Y . Meng, V . V . Struzhkin, and R. J. Hemley, Evidence for Superconductivity above 260 K in Lanthanum Superhydride at Megabar Pressures, Phys. Rev. Lett. 122, 027001 (2019)

work page 2019

[14] [14]

Murakami, K

M. Murakami, K. Hirose, K. Kawamura, N. Sata, and Y . Ohishi, Post -perovskite phase transition in MgSiO3, Science 304, 855 (2004)

work page 2004

[15] [15]

Tateno, K

S. Tateno, K. Hirose, Y . Ohishi, and Y . Tatsumi, The structure of iron in Earth's inner core, Science 330, 359 (2010)

work page 2010

[16] [16]

Anzellini, A

S. Anzellini, A. Dewaele, M. Mezouar, P. Loubeyre, and G. Morard, Melting of iron at Earth's inner core boundary based on fast X-ray diffraction, Science 340, 464 (2013)

work page 2013

[17] [17]

Giampaoli, I

R. Giampaoli, I. Kantor, M. Mezouar, S. Boccato, A. D. Rosa, R. Torchio, G. Garbarino, O. Mathon, and S. Pascarelli, Measurement of temperature in the laser-heated diamond anvil cell: comparison between reflective and refractive optics, High Pressure Research 38, 250 -269 (2018)

work page 2018

[18] [18]

C. E. Yen, Q. Williams and M. Kunz, Thermal Pressure in the Laser -Heated Diamond Anvil Cell: A Quantitative Study and Implications for the Density Versus Mineralogy Correlation of the Mantle, J. Geophys. Res. Solid Earth 125, e2020JB020006 (2020)

work page 2020

[19] [19]

Takizawa, M

H. Takizawa, M. Shimada, Y . Sato , T. Endo, High -pressure synthesis of MnSb 2 with the marcasite-type structure, Mat. Lett. 18, 11 (1993). 22

work page 1993

[20] [20]

M. Xu, M. Boswell, Q. Ding, P. Cheng, A. Sapkota, Q. Zhang, D. Yahne, S. L. Bud'ko, Y . Furukawa, P. C. Canfield, R. A. Ribeiro, W. Xie, Pressure -Stabilized MnSb 2 with Complex Incommensurate Magnetic Order, arXiv preprint arXiv:2603.09635 (2026)

work page arXiv 2026

[21] [21]

D. A. Salamatin, K. V . Klementiev, V . N. Krasnorussky, M. V . Magnitskaya, N. M. Chtchelkachev, V . A. Sidorov, A. V . Semeno, A. V . Bokov, M. G. Kozin, A. V . Nikolaev, A. V . Salamatin, A. Velichkov, M. V . Mikhin, M. Budzynski, and A. V . Tsvyashchenko, J. Alloys Compd. 946, 169275 (2023)

work page 2023

[22] [22]

Bjscistar, https://www.bjscistar.com/page169?product_id=82

work page

[23] [23]

Bjscistar, http://www.bjscistar.com/page169?product_id=127

work page

[24] [24]

Dewaele, M

A. Dewaele, M. Torrent, P. Loubeyre et al., Compression curves of transition metals in the Mbar range: Experiments and projector augmented-wave calculations. Phys. Rev. B 78 (10), 104102 (2008)

work page 2008

[25] [25]

G. Shen, Y . Wang, A. Dewaele et al., Toward an international practical pressure scale: A proposal for an IPPS ruby gauge (IPPS-Ruby2020), High Press. Res. 40, 299–314 (2020)

work page 2020

[26] [26]

Prescher, and V

C. Prescher, and V . B. Prakapenka, DIOPTAS: a program for reduction of two-dimensional x- ray diffraction data and data exploration, High. Press. Res. 35, 223–230 (2015)

work page 2015

[27] [27]

B. H. Toby, and R. B. V on Dreele, GSAS-II: the genesis of a modern open -source all-purpose crystallography software package, J. Appl. Crystallogr. 46, 544–549 (2013)

work page 2013

[28] [28]

Wittig, A study of the superconductivity of antimony under pressure and a search for superconductivity in arsenic, Journal of Physics and Chemistry of Solids, 30, 1407-1410 (1969)

J. Wittig, A study of the superconductivity of antimony under pressure and a search for superconductivity in arsenic, Journal of Physics and Chemistry of Solids, 30, 1407-1410 (1969)

work page 1969