The asymmetric carbon-rich chemistry of the planet-forming disk of HD 142527 triggered by late infall

The planet-forming disk of HD 142527 is known for its azimuthally asymmetric dust trap, shadows, and spiral arms. We use new ALMA observations to investigate the molecular composition and to determine the ongoing chemical processes and the origin of its asymmetric molecular emission. The observations cover a wide variety of molecular species, enlarging the known molecular inventory of this system. Strikingly, the emission of H$_2$CO, CN, and C$_2$H is dominated by spiral-like features peaking in the southern region of the disk, opposite to the large dust trap, while no relation is found between the observed asymmetries and the shadows seen in the scattered light. We attribute these features to low-density, late infalling, atomic carbon-rich material that locally enhances the C/O-ratio and, subsequently, facilitates the gas-phase formation of these species. The emission of C$^{17}$O and the HCO$^+$ $J$=1-0 transition is aligned with the large dust trap, likely due to an azimuthal enhancement in the surface density. Differences between the two observed C$^{17}$O transitions may be due to dust obscuration effects. This is not expected to affect molecular emission at 3 millimetres, given the lower optical depth of the dust trap. The four observed transitions of CS display different azimuthal extents and strengths, with the lines with lower upper level energies appearing more ring-like. An analysis of the $^{13}$CO brightness temperature yields no significant azimuthal temperature variations. Therefore, we propose that the observed CS transitions trace two different reservoirs: a cold reservoir that resides on a Keplerian orbit and a second, hotter reservoir of CS that is facilitated by the infalling material. A single weak transition of SO is observed, which may be explained by weak shocks induced by the spirals observed in the scattered light that liberate sulphur.