The Roasting Marshmallows Program with IGRINS on Gemini South V: Atmosphere of MASCARA-1b is Enriched in Refractory Elements

Ultra-hot Jupiters (UHJs; $T_{\rm eq} \gtrsim 2000$ K) enable simultaneous detection of volatile (ice-forming) and refractory (rock-forming) species in planetary atmospheres, providing a powerful diagnostic of planet formation and atmospheric processing. We present a comprehensive high-resolution cross-correlation spectroscopy (HRCCS) analysis of the UHJ MASCARA-1b ($T_{\rm eq} \approx 2600$ K) using the IGRINS and IGRINS-2 spectrographs. We detect robust (SNR$>$4) signals from H$_2$O, CO, OH, Fe I, Mg I, Ca I, and Ti I, marking the most complete atmospheric inventory of MASCARA-1b to date. Using a chemically consistent atmospheric inference framework, we constrain elemental abundances to a typical precision of $\approx$0.2 dex, retrieving a solar atmospheric metallicity ([M/H]$_\odot$ $= 0.07^{+0.17}_{-0.13}$ $\approx 1.2\times$ solar), a C/O ratio (C/O $= 0.65^{+0.08}_{-0.08}$) consistent with solar value (C/O $=$ 0.59), an enhanced refractory abundance ([R/H]$_\odot$ $= 0.40^{+0.23}_{-0.17} \approx 2.5\times$ solar; $\approx 3.8\times$ stellar), and a moderately super-solar refractory-to-volatile ratio ([R/V]$_\odot$ $= 0.36^{+0.11}_{-0.09}$ $\approx 2.3\times$ solar). Comparison with formation models suggests that MASCARA-1b most likely accreted material between the soot-H$_2$O or H$_2$O-CO snowlines (at 68$\%$ confidence). We additionally find stellar values for atmospheric Ti/Mg and Ca/Mg ratios (at 68$\%$ confidence). The Mg/Fe is also found to be consistent with stellar value at 95$\%$ confidence. Therefore, we do not find strong indication of nightside cold trapping in MASCARA-1b. As homogeneous refractory-to-volatile measurements expand across the UHJ population, particularly with upcoming Extremely Large Telescopes, these diagnostics will enable statistically robust tests of emerging trends in giant planet formation and atmospheric evolution.