Density fluctuations and entropy
read the original abstract
A new functional for the entropy that is asymptotically correct both in the high and low density limits is proposed. The new form is [ S=S^{(id)}+S^{(ln)}+S^{(r)}+S^{(c)} ] where the new term S^{(c)} depends on the p-bodies density fluctuations $\alpha_p$ and has the form [ S^{(c)}= <N> {ln 2-1+\sum_{p=2}^\infty \frac{(\ln 2) ^p}{p!}\alpha_p-[ \exp (\alpha_2-1)-\alpha_2]} +\hat S ], where $\hat S$ renormalizes the ring approximation S^{(r)}. This result is obtained by analyzing the functional dependence of the most general expression of the entropy: Two main results for S^{(c)} are proven: i) In the thermodynamic limit, only the functional dependence on the one body distribution function survives and ii) by summing to infinite order the leading contributions in the density a new numerical expression for the entropy is proposed with a new renormalized ring approximation included. The relationship of these results to the incompressible approximation to entropy is discussed.
This paper has not been read by Pith yet.
discussion (0)
Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.