The dynamics of a hole in a CuO₄ plaquette: electron energy-loss spectroscopy of Li₂CuO₂
classification
❄️ cond-mat
keywords
electronenergy-lossmodelplaquettesinglespectroscopywellcharge
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We have measured the energy and momentum dependent loss function of Li_2CuO_2 single crystals by means of electron energy-loss spectroscopy in transmission. Using the same values for the model parameters, the low-energy features of the spectrum as well as published Cu 2p_(3/2) x-ray photoemission data of Li_2CuO_2 are well described by a cluster model that consists of a single CuO_4 plaquette only. This demonstrates that charge excitations in Li_2CuO_2 are strongly localized.
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